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- Melting in confined systems: Monte Carlo simulations of Kr in nano-pores of MCM-41

Auteur(s): Kuchta B., Denoyel R., Firlej L.

(Article) Publié: Colloids And Surfaces A: Physicochemical And Engineering Aspects, vol. 241 p.143-148 (2004)


Résumé:

Melting of krypton confined in 4 nm MCM-41 pore has been studied. A continuous melting, starting from the pore center, has been observed in various thermodynamic conditions: along the saturation line, at constant pressure and at constant number of atoms. The crucial role of the atom-wall interaction has been discussed, particularly its influence on an increase or a reduction of the melting temperature. (C) 2004 Elsevier B.V. All rights reserved.



Commentaires: Article 0927-7757 Sp. Iss. SI