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- Polymerization of conducting polymers inside carbon nanotubes hal link

Auteur(s): Steinmetz Jean, Kwon S., Lee H.J., Abou-Hamad E., Almairac Robert, Goze-Bac C., Kim H., Park Y.W.

(Article) Publié: Chemical Physics Letters, vol. 431 p.139-144 (2006)


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Résumé:

Supercritical carbon dioxide is an universal tool to impregnate carbon nanotubes with a wide range of organic molecules. In this Letter, we present our results of carbon nanotubes filled with the photo-conducting polymer poly(N-vinyl carbazole) and the conducting polymer polypyrrole which were prepared by polymerizing the monomers inside the nanotubes. The endohedral nanotubes were characterized by HRTEM and H-1 NMR which confirmed that the encapsulated material was indeed the conducting polymer. (c) 2006 Elsevier B.V. All rights reserved.