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- Temperature dependence and pressure dependence of the vibrational properties of corannulene doi link

Auteur(s): Alvarez L., Le Parc R., Jourdain V., Dennler S., Bantignies J.-L., Sauvajol J.-L., Rose Jonathan A., Scott Lawrence T.

(Article) Publié: Physica Status Solidi B, vol. 245 p.2261-2263 (2008)
Texte intégral en Openaccess : istex


Ref HAL: hal-00496491_v1
DOI: 10.1002/pssb.200879611
WoS: 000260581800086
Exporter : BibTex | endNote
4 Citations
Résumé:

Herein, we report the experimental investigation of the vibrational properties of corannulene using Raman spectroscopy. The temperature dependences of the Raman spectra between 300 and 20 K reveal a very high sensitivity of the low frequency domain between 40 and 200 cm(-1) compared to the intramolecular domain. The behavior of the Raman modes of the corannulene under pressure, between 0.53 GPa and 8 GPa, is also studied. Under pressure, in the intermolecular vibrational domain (<150 cm(-1)), two transitions occur suggesting metastable intermediate stages under pressure. (C) 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim