• Physique/Matière Condensée/Science des matériaux
  

Both Classical and Quantum Electrodynamics predict the existence of dipole-dipole long-range electrodynamic intermolecular forces, however these have never been hitherto experimentally observed. The discovery of completely new and unanticipated forces acting between biomolecules could have considerable impact on our understanding of the dynamics and functioning of the molecular machines at work in living organisms. Here, using two independent approaches, we demonstrate experimentally for the first time the activation of resonant electrodynamic intermolecular forces. We characterize clustering transitions induced by these forces by fluorescence correlation spectroscopy when out-of-equilibrium conditions induce collective molecular oscillation observed by Terahertz (THz) spectroscopy. This is an unprecedented experimental \textit{proof of principle} of a physical phenomenon that, having been observed for bio-macromolecules and with a long-range of action (up to 1000 ${\mathring{A}}$), could be of importance for biology. Therefore, in addition to thermal fluctuations that drive molecular motion randomly, these resonant (and thus selective) electrodynamic forces may contribute to molecular encounters in the crowded cellular space. We anticipate our findings will provide a basis for future systematic deepening of physical aspects of the reported phenomena and for future systematic assessment of the relevance of electrodynamic forces in shaping the dynamics of biomolecular encounters and recognition in biology.

Magneto-absorption in HgTe/CdHgTe quantum wells with an inverted band structure in magnetic fields up to 30 T has been studied. It has been shown that the positions of magneto-absorption lines for transitions from the zero-mode Landau levels in a wide range of magnetic field cannot in principle be described in the “single-electron” approximation using the eight-band Kane model even taking into account effects associated with the absence of spatial inversion symmetry. The revealed dependence of the energies of optical transitions on the magnetic field can be qualitatively explained within a “many-body” picture, where transitions between Landau levels are considered as collective modes hybridized by the electron-electron interaction.

We investigated quantum Hall states in an inverted HgTe quantum well (QW) close to the critical thickness using transconductance fluctuation (TF) measurements. In the conduction band, several integer quantum Hall states were observed, corresponding to filling factors ν=1,2,3,4. For magnetic fields above 2 T, quantum Hall states ν=0 were observed in the normal gap. These observations agreed well with the previous studies of quantum Hall states on GaAs QWs and graphene. Interestingly, TFs corresponding to anomalous positive filling factor ν were clearly observed in the valence band. We attribute the emergence of those TFs to the localization and charging of the heavy holes located in the side maxima of the valence band.

We report on the far-infrared magnetospectroscopy of HgTe quantum wells with inverted band ordering at different electron concentrations. We particularly focus on optical transitions from zero-mode Landau levels, which split from the edges of electron-like and hole-like bands. We observe a pronounced dependence of the transition energies on the electron concentration varied by persistent photoconductivity effect. This is striking evidence that in addition to the already well-documented crystalline and interface asymmetries, electron-electron interactions also have a significant impact on the usual behavior of the optical transitions from zero mode Landau levels.

The features of terahertz photoluminescence and magnetoabsorption in magnetic fields up to 16 T in threelayer InAs/GaSb/InAs quantum wells with a band structure corresponding to a “two-dimensional semimetal” are studied. The comparison of the positions and amplitudes of the photoluminescence lines with the theoretical calculations of oscillator strengths for interband and intraband transitions performed using the eight-band Kane Hamiltonian indicates the existence of a nonradiative recombination channel associated with the overlap of the conduction and valence bands. The energies of interband and intraband Landau level transitions observed in the magnetoabsorption spectra are in good agreement with theoretical calculations, which confirms the predicted band structure.