Ref HAL: hal-03194024_v1
DOI: 10.1039/d0nj05933a
WoS: WOS:000623596600015
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Pesticide sensing is an important object of study due to its increasing use worldwide. Herein, we report a SERS study of 4-nitrophenol (PNP), which is product of neutralization processes of various pesticides such as Paraoxon, and can be used as a target molecule for monitoring. PNP is also widely used in the chemical industry and due to its high toxicity is considered a concerning pollutant. The sensing was carried out with a reduced graphene oxide nanocomposite functionalized with cysteamine and Ag nanoparticles (rGOSHAg), and compared with raw reduced graphene oxide and a commercial SERS substrates (SERStrate (TM)). A mechanistic evaluation was also carried out, focused in the degradation of PNP caused by the different exciting laser lines, evidencing the PNP dimerization in substrates containing Ag NPs (under 532 nm laser), which has important outcomes for sensing purposes. The nanocomposite rGOSHAg presented the highest sensitivity towards PNP, detecting concentrations as low as 10(-6) mol L-1 and with a high potential for field applications and real-time measurements of molecules commonly present in pesticides and industrial contaminants.

Ref HAL: hal-03189697_v1
DOI: 10.3390/polym13071153
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PNIPAm microgels synthesized via free radical polymerization (FRP) are often considered as neutral colloids in aqueous media, although it is well known, since the pioneering works of Pelton and coworkers, that the vanishing electrophoretic mobility characterizing swollen microgels largely increases above the lower critical solution temperature (LCST) of PNIPAm, at which microgels partially collapse. The presence of an electric charge has been attributed to the ionic initiators that are employed when FRP is performed in water and that stay anchored to microgel particles. Combining dynamic light scattering (DLS), electrophoresis, transmission electron microscopy (TEM) and atomic force microscopy (AFM) experiments, we show that collapsed ionic PNIPAm microgels undergo large mobility reversal and reentrant condensation when they are co-suspended with oppositely charged polyelectrolytes (PE) or nanoparticles (NP), while their stability remains unaffected by PE or NP addition at lower temperatures, where microgels are swollen and their charge density is low. Our results highlight a somehow double-faced electrostatic behavior of PNIPAm microgels due to their tunable charge density: they behave as quasi-neutral colloids at temperature below LCST, while they strongly interact with oppositely charged species when they are in their collapsed state. The very similar phenomenology encountered when microgels are surrounded by polylysine chains and silica nanoparticles points to the general character of this twofold behavior of PNIPAm-based colloids in water.

Ref HAL: hal-03191119_v1
DOI: 10.1103/PhysRevB.103.155404
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Twisted two-dimensional bilayer anisotropy materials exhibit many exotic physical phenomena. Manipulating the “twist angle” between the two layers enables the hybridization phenomenon of polaritons, resulting in fine control of the dispersion engineering of the polaritons in these structures. Here, combined with the hybridization phenomenon of anisotropy polaritons, we study theoretically the near-field radiative heat transfer (NFRHT) between two twisted hyperbolic systems. These two twisted hyperbolic systems are mirror images of each other. Each twisted hyperbolic system is composed of two graphene gratings, where there is an angle φ between these two graphene gratings. By analyzing the photonic transmission coefficient as well as the plasmon dispersion relation of the twisted hyperbolic system, we prove the enhancement effect of the topological transitions of the surface state at a special angle [from open (hyperbolic) to closed (elliptical) contours] on radiative heat transfer. Meanwhile the role of the thickness of dielectric spacer and vacuum gap on the manipulating the topological transitions of the surface state and the NFRHT are also discussed. We predict the hysteresis effect of topological transitions at a larger vacuum gap, and demonstrate that as the thickness of the dielectric spacer increases, the transition from the enhancement effect of heat transfer caused by the twisted hyperbolic system to a suppression.

Ref HAL: hal-03186214_v1
Ref Arxiv: 2103.06721
Ref INSPIRE: 1851112
DOI: 10.1103/PhysRevD.104.046003
Ref. & Cit.: NASA ADS
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We find a parametrically light dilaton in special confining theories in three dimensions. Their duals form what we call a scion of solutions to the supergravity associated with the large-$N$ limit of the Coulomb branch of the $\mathcal{N}=4$ Super-Yang-Mills theory. The supergravity description contains one scalar with bulk mass that saturates the Breitenlohner-Freedman unitarity bound. The new solutions are defined within supergravity, they break supersymmetry and scale invariance, and one dimension is compactified on a shrinking circle, yet they are completely regular. An approximate dilaton appears in the spectrum of background fluctuations (or composite states in the confining theory), and becomes parametrically light along a metastable portion of the scion of new supergravity solutions, in close proximity of a tachyonic instability. A first-order phase transition separates stable backgrounds, for which the approximate dilaton is not parametrically light, from metastable and unstable backgrounds, for which the dilaton becomes parametrically light, and eventually tachyonic.

Ref HAL: hal-03184640_v1
Ref Arxiv: 2102.13214
DOI: 10.1016/j.coastaleng.2021.103976
WoS: WOS:000702874300002
Ref. & Cit.: NASA ADS
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The Miles theory of wave amplification by wind is extended to the case of finite depth h and a shear flow with (constant) vorticity {\Omega}. Vorticity is characterised through the non-dimensional parameter {\nu} = {\Omega} U_1 /g, where g the gravitational acceleration, U_1 a characteristic wind velocity and k the wavenumber. The notion of 'wave age' is generalised to account for the effect of vorticity. Several widely used growth rates are derived analytically from the dispersion relation of the wind/water interface, and their dependence on both water depth and vorticity is derived and discussed. Vorticity is seen to shift the maximum wave age, similar to what was previously known to be the effect of water depth. At the same time, a novel effect arises and the growth coefficients, at identical wave age and depth, are shown to experience a net increase or decrease according to the shear gradient in the water flow.

Ref HAL: hal-03184622_v1
Ref Arxiv: 2102.02486
Ref. & Cit.: NASA ADS
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We extend the paradigmatic and versatile TASEP (Totally Asymmetric Simple Exclusion Process) for stochastic 1d transport to allow for two different particle species, each having specific entry and exit rates. We offer a complete mean-field analysis, including a phase diagram, by mapping this model onto an effective one-species TASEP. Stochastic simulations confirm the results, but indicate deviations when the particle species have very different exit rates. We illustrate that this is due to a phenomenon of intermittency, and formulate a refined 'intermittent' mean-field (iMF) theory for this regime. We discuss how non-stationary effects may further enrich the phenomenology.

Ref HAL: hal-03184607_v1
DOI: 10.1103/PhysRevD.103.023526
WoS: WOS:000609014700004
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We consider the possibility that the dark sector of our Universe contains a negative cosmological constant dubbed λ. For such models to be viable, the dark sector should contain an additional component responsible for the late-time accelerated expansion rate (X). We explore the departure of the expansion history of these models from the concordanceΛ cold dark matter (ΛCDM) model. For a large class of our models, the accelerated expansion is transient with a nontrivial dependence on the model parameters. All models with wX>−1 will eventually contract and we derive an analytical expression for the scale factor a(t) in the neighborhood of its maximal value. We find also the scale factor for models ending in a Big Rip in the regime where dustlike matter density is negligible compared to λ. We address further the viability of such models, in particular when a high H0 is taken into account. While we find no decisive evidence for a nonzero λ, the best models are obtained with a phantom behavior on redshifts z≳1 with a higher evidence for nonzero λ. An observed value for h substantially higher than 0.70 would be a decisive test of their viability.