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Core-Shell Microgel-Based Surface Coatings with Linear Thermoresponse ![]() Auteur(s): Cors M., Wrede Oliver, Genix A.-C., Anselmetti Dario, Oberdisse J., Hellweg Thomas
(Article) Publié:
Langmuir, vol. 33 p.6804-6811 (2017)
Texte intégral en Openaccess : Ref HAL: hal-01580200_v2 Ref Arxiv: 1811.08753 DOI: 10.1021/acs.langmuir.7b01199 WoS: WOS:000405536100019 Ref. & Cit.: NASA ADS Exporter : BibTex | endNote 28 Citations Résumé: We study the swelling and shrinking behavior of core-shell microgels adsorbed on silicon wafers. In these systems, the core is made of cross-linked poly(N isopropylmethacrylamide) and the shell consists of cross linked poly(N-n propylacrylamide). In suspension, these particles exhibit an extended linear swelling behavior in the temperature interval between the lower critical solution temperatures of the two polymers. Using ellipsometry and AFM, we show that this linear response is also observed in the adsorbed state. |