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- Selective growth of large chiral angle single-walled carbon nanotubes

Auteur(s): Paillet M., Meyer Jannik c., Michel T., Jourdain V., Poncharal Philippe, Sauvajol J.-L., Cordente Nadege, Amiens Catherine, Chaudret Bruno, Roth Siegmar, Zahab A. A.

Conference: 16th European Conference on Diamond, Diamond-Like Materials, Carbon Nanotubes, and Nitrides (Toulouse (FRANCE), FR, 2005-09-11)
Actes de conférence: DIAMOND AND RELATED MATERIALS, vol. 15 p.1019-1022 (2006)


Résumé:

We have developed a versatile catalyst-assisted chemical vapor deposition (CVD) technique for the synthesis of single-walled carbon nanombes (SWNTs) from discrete nickel nanoparticles (average diameter of 4.7 +/- 1.5 nm). Atomic force microscopy (AFM), transmission electron microscopy (TEM) and electron diffraction are used to characterize these as-grown nanombes. On a particular sample we found that the SWNTs have an average chiral angle of 25.3 degrees. This result shows that a control of the chiral angle of SWNT with large diameters (mean diameter = 1.75 nm) and with a relatively broad diameter distribution (standard deviation = 0.5 nm) is achievable to a certain extent. (c) 2006 Elsevier B.V. All rights reserved.