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- Multiscale investigation of graphene layers on 6H-SiC(000-1) doi link

Auteur(s): Tiberj A., Huntzinger J.-R., Camassel J., Hiebel Fanny, Mahmood Ather, Mallet Pierre, Naud Cécile, Veuillen Jean-Yves

(Article) Publié: Nanoscale Research Letters, vol. 6 p.171 (2011)
Texte intégral en Openaccess : openaccess


Ref HAL: hal-00666156_v1
DOI: 10.1186/1556-276X-6-171
WoS: 000290525700090
Exporter : BibTex | endNote
14 Citations
Résumé:

In this article, a multiscale investigation of few graphene layers grown on 6H-SiC(000-1) under ultrahigh vacuum (UHV) conditions is presented. At 100-mu m scale, the authors show that the UHV growth yields few layer graphene (FLG) with an average thickness given by Auger spectroscopy between 1 and 2 graphene planes. At the same scale, electron diffraction reveals a significant rotational disorder between the first graphene layer and the SiC surface, although well-defined preferred orientations exist. This is confirmed at the nanometer scale by scanning tunneling microscopy (STM). Finally, STM (at the nm scale) and Raman spectroscopy (at the mu m scale) show that the FLG stacking is turbostratic, and that the domain size of the crystallites ranges from 10 to 100 nm. The most striking result is that the FLGs experience a strong compressive stress that is seldom observed for graphene grown on the C face of SiC substrates.