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- Analysis of sodium copper chlorophyllin and sodium magnesium chlorophyllin by time-domain THz spectroscopy doi link

Auteur(s): Bray C., Diakonova N., O'Connor Emma, Brouillet Etienne, Meriguet Y., Nelson David, Faulds Karen, Torres Jeremie, Coquillat D.

Conference: 2022 47th International Conference on Infrared, Millimeter and Terahertz Waves (IRMMW-THz) (Delft, FR, 2022-08-28)

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Ref HAL: hal-03837865_v1
DOI: 10.1109/IRMMW-THz50927.2022.9895466
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Résumé:

The terahertz absorption spectra of sodium magnesium chlorophyllin (Chl-Mg-Na) and sodium copper chlorophyllin (Cu-Chl), two major members of the chlorophyll derivative family, have been measured in the range 0.2−2.5 THz, at room temperature. The capability of terahertz spectroscopy for quantitative characterization of Chl-Mg-Na intermolecular vibrations was investigated and the sensitivity of transitions with degree of hydration by changes in the molecular environment was examined. For the Cu-Chl derivative, a broad feature was observed around 1.8 THz which currently hinders clear Cu-Chl identification and quantification.