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(174) Production(s) de ANGLARET E.
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Carbon Nanotubes Induced Gelation of Unmodified Hyaluronic Acid
Auteur(s): Zamora-Ledezma C., Buisson Lionel, E. Moulton Simon, Wallace Gordon, Zakri Cécile, Blanc C., Anglaret E., Poulin Philippe
(Article) Publié:
Langmuir, vol. 29 p.10247−10253 (2013)
Texte intégral en Openaccess :
Ref HAL: hal-00870751_v1
DOI: 10.1021/la4016492
WoS: 000323193100036
Exporter : BibTex | endNote
12 Citations
Résumé: This work reports an experimental study of the kinetics and mechanisms of gelation of carbon nanotubes (CNTs)−hyaluronic acid (HA) mixtures. These materials are of great interest as functional biogels for future medical applications and tissue engineering. We show that CNTs can induce the gelation of noncovalently modified HA in water. This gelation is associated with a dynamical arrest of a liquid crystal phase separation, as shown by small-angle light scattering and polarized optical microscopy. This phenomenon is reminiscent of arrested phase separations in other colloidal systems in the presence of attractive interactions. The gelation time is found to strongly vary with the concentrations of both HA and CNTs. Near-infrared photoluminescence reveals that the CNTs remain individualized both in fluid and in gel states. It is concluded that the attractive forces interplay are likely weak depletion interactions and not strong van der Waals interactions which could promote CNT rebundling, as observed in other biopolymer−CNT mixtures. The present results clarify the remarkable efficiency of CNT at inducing the gelation of HA, by considering that CNTs easily phase separate as liquid crystals because of their giant aspect ratio.
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Optical spectroscopic studies of single-wall carbon nanotubes :
growth mechanism, and anisotropic composites
Auteur(s): Anglaret E.
(Séminaires)
Universidad Los Andes, dpt of physics (Merida, VE), 2013-02-06 |
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Optical spectroscopic studies of single-wall carbon nanotubes :
growth mechanism, and anisotropic composites
Auteur(s): Anglaret E.
(Séminaires)
Universidade Federal de Minas Gerais, dpt of physics (Belo Horizonte, BR), 2013-02-18 |
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Inkjet printing of carbon nanotubes
Auteur(s): Anglaret E.
Conférence invité: ENANO2013, school on Nanoscience and nanotechnology (Choroni, VE, 2013-01-20)
Ref HAL: hal-00806563_v1
Exporter : BibTex | endNote
Résumé: Photolithography process are classically used to manufacture electronic devices. Printing techniques are presently developed as simple and cheap alternatives. Among the different printing techniques, inkjet printing offers a simple, direct and contactless process, with a resolution at the micron scale. In this lecture, we will present the fundamental and technical issues of the inkjet technique, as well as some basic requirements for the inks. We will then focus on the printing of conductive patterns by inkjet, essentially from metallic nanoparticles or carbon nanomaterials (carbon nanotubes, graphene). We will especially discuss the formulation of the inks, the microstructure of the printed patterns and their electrical properties.
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Liquid crystals of carbon nanotubes and graphene
Auteur(s): Zakri Cécile, Blanc C., Grelet Eric, Zamora-Ledezma C., Puech Nicolas, Anglaret E., Poulin Philippe
(Article) Publié:
Philosophical Transactions Of The Royal Society Of London. Series A, Containing Papers Of A Mathematical Or Physical Character, vol. 371 p.pp. 1-15 (2013)
Texte intégral en Openaccess :
Ref HAL: hal-00797442_v1
DOI: 10.1098/rsta.2012.0499
WoS: 000315792800013
Exporter : BibTex | endNote
53 Citations
Résumé: Liquid crystal ordering is an opportunity to develop novel materials and applications with spontaneously aligned nanotubes or graphene particles.Nevertheless, achieving high orientational order parameter and large monodomains remains a challenge. In addition, our restricted knowledge of the structure of the currently available materials is a limitation for fundamental studies and future applications. This paper presents recent methodologies that have been developed to achieve large monodomains of nematic liquid crystals. These allow quantification and increase of their order parameters. Nematic ordering provides an efficient way to prepare conductive films that exhibit anisotropic properties. In particular, it is shown how the electrical conductivity anisotropy increases with the order parameter of the nematic liquid crystal. The order parameter can be tuned by controlling the length and entanglement of the nanotubes. In the second part of the paper, recent results on graphene liquid crystals are reported. The possibility to obtain water-based liquid crystals stabilized by surfactant molecules is demonstrated. Structural and thermodynamic characterizations provide indirect but statistical information on the dimensions of the graphene flakes. From a general point of view, this work presents experimental approaches to optimize the use of nanocarbons as liquid crystals and provides new methodologies for the still challenging characterization of such materials.
Commentaires: 15 pages
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Dispersion and orientation of single-walled carbon nanotubes in a chromonic liquid crystal
Auteur(s): Ould-Moussa Nawell, Blanc C., Zamora-Ledezma C., D. Lavrentovich Oleg, I. Smalyukh Ivan, F. Islam Mohammad, G. Yodh A., Maugey Maryse, Poulin Philippe, Anglaret E., Nobili M.
(Article) Publié:
Liquid Crystals, vol. 40 p.1628-1635 (2013)
Ref HAL: hal-00794735_v1
DOI: 10.1080/02678292.2013.772254
WoS: 000328245700005
Exporter : BibTex | endNote
49 Citations
Résumé: A post-synthesis alignment of individual single-walled carbon nanotubes (SWCNTs) is desirable for translating their unique anisotropic properties to a macroscopic scale. Here, we demonstrate excellent dispersion, orientation and concomitant-polarised photoluminescence of SWCNTs in a nematic chromonic liquid crystal. The methods to obtain stable suspension are described, and order parameters of the liquid crystal matrix and of the nanotubes are measured independently.
Commentaires: 8 pages
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Metrology of nanomaterials
Auteur(s): Anglaret E.
(Séminaires)
Atotech GmbH (Berlin, DE), 2012-07-19 |