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Ref Arxiv: 2509.19942
DOI: 10.1021/acs.langmuir.5c04088
Ref. & Cit.: NASA ADS
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The thermosensitivity and microstructure of microgels made by copolymerizing standard microgelforming monomers with more hydrophilic comonomers is investigated, with the aim of increasing the volume phase transition temperature (VPTT). We precisely determine the incorporation of N-(hydroxymethyl)acrylamide (HMAM) and purpose-synthesized N-(2-hydroxyisopropyl)acrylamide (HIPAM) into microgels-neither of which forms microgels on its own by precipitation polymerization. The swelling properties and microstructure of the resulting copolymer microgels with Nisopropylacrylamide (NIPAM, LCST ca. 32°C) and N-isopropylmethacrylamide (NIPMAM, LCST ca. 44°C) are then characterized via turbidimetry, DLS, and AFM. At low comonomer contents, all microgel particles exhibit moderate growth in size. Beyond a system-specific threshold, we observe a significant jump in size, and smoother swelling behavior. For NIPAM-HIPAM, the size increase is linked to a strong rise in swelling capacity, and the formation of a thick corona. The effect of the hydrophilic comonomers on the VPTT correlates linearly with their true composition, allowing us to extrapolate the VPTT of hypothetical pure HMAM and HIPAM microgels. This leads to 99°C for HMAM, and 68°C for HIPAM for the respective VPTT. These numbers can be seen as useful indicators of the effect of these monomers on the VPTT in the copolymerized microgels. The observed changes in VPTT, swelling, size, and morphology suggest that high-VPTT microgels possess unique internal molecular composition gradients, likely due to hydrophobic interactions during synthesis. Our results have potential implications for developing temperature-sensitive microgel-based membranes that can self-adapt their permeability at higher operating temperatures in energy applications.

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Gravity affects the flow and the behavior at rest of complex fluids and flows by inducing sedimentation, drainage, and interfacial deformation, which can mask more fundamental physical processes. On Earth, standard countermeasures against gravity come with limitations in terms of possible formulations or the quality and homogeneity of the applied strain. Alternatively, one can run these experiments in free-fall or in orbit where the effects of gravity are canceled i.e., under microgravity conditions. In this short review, we present several European Space Agency-led projects of interest to rheologists that leverage microgravity environments: FAST/FASTER , which studies interfacial rheology using Capillary Pressure Tensiometers; SMD-FOAM, fundamental experiments on foam coarsening ; SMD-PASTA and SEEDS, aimed at understanding the dynamics of emulsion droplets, its evolution and microrheology using Diffusing Wave Spectroscopy; results associated with studies on granular materials in microgravity, including AstEx and CompGran; COLIS, which examines the thermally driven perturbation of soft colloidal glasses monitored by Dynamic Light Scattering; BIOMICS/KRABS, investigating the aggregation and migration of soft particles and red blood cells under flow. Microgravity experiments allowed for high-precision measurements of interfacial viscoelasticity, detailed studies of emulsion aging and drop coalescence, observed plastic rearrangements in colloidal glasses, characterized the dynamics under flow of red blood cell analogues, and rationalized the impact of gravity on convection and fluidization in agitated granular matter. Collectively, these experiments demonstrate the complementarity and the relevance of ESA's microgravity platforms in expanding the frontiers of soft matter rheology.

Commentaires: Accepted for publication in Journal of Rheology

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DOI: 10.1371/journal.pone.0333021
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Plastic pollution is a major and global threat to ecosystems and human health, resulting from the spreading and breakdown of plastic litter in the environment. In an aquatic environment, the first causes of this degradation are exposure to natural ultraviolet light and abrasion or collisions in the water. The extent of such degradation on a plastic object after a given time remains very difficult to quantify, especially regarding the relative production of microplastics, nanoplastics and soluble species along with volatile compounds. All of these degradation products may contribute differently to environmental pollution. Therefore, when evaluating the pollution caused by plastic objects, we should consider how much of each byproduct is generated. We propose a novel method based on conservation of the carbon mass during the degradation process. This approach is the first to enable quantification of carbon retrieved in each type of degradation product (Microplastics, Nanoplastics, Solubles, Volatile Compounds), as well as its evolution with exposure time. By applying this method to polypropylene granules, we demonstrate its effectiveness in tracking carbon footprint throughout the aging process. One of the unexpected results of this study is to show that the amount of carbon released in volatile form is far from negligible (17%) compared to MP (55%). The procedure we present is general enough to be applied to any type of polymer, and can be a valuable tool for assessing the amount of by-products of a given size released into the environment.

Ref HAL: hal-05335459_v1
DOI: 10.1038/s41467-025-64557-x
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Bacteria’s ability to withstand mechanical challenges is enhanced in their biofilm lifestyle, where they are encased in a viscoelastic polymer matrix. Under fluid flow, biofilms can form as streamers – slender filaments tethered to solid surfaces and suspended in the flowing fluid. Streamers thrive in environments subjected to intense hydrodynamic stresses, such as medical devices and water filters, often resulting in catastrophic clogging. Their colonisation success may depend on a highly adaptable mechanical response to varying stress conditions, though the evidence and underlying mechanisms of this adaptation remain elusive. Here, we demonstrate that biofilm streamers exhibit a stress-hardening behaviour, with both differential elastic modulus and effective viscosity increasing linearly with external stress. This stress-hardening is consistent across biofilms with different matrix compositions, formed by various bacterial species, and under diverse growth conditions. We further demonstrate that this mechanical response originates from the properties of extracellular DNA (eDNA) molecules, which constitute the structural backbone of the streamers. In addition, our results identify extracellular RNA (eRNA) as a modulator of the matrix network, contributing to both the structure and rheological properties of the eDNA backbone. Our findings reveal an instantaneous, purely physical mechanism enabling streamers to adapt to hydrodynamic stresses. Given the ubiquity of extracellular nucleic acids (eNA) in biofilms, this discovery prompts a re-evaluation of their functional role in biofilm mechanics, with potential implications for biofilm structural integrity, ecological resilience, and colonisation dynamics.

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DOI: 10.1021/acs.macromol.4c03215
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Colloids are widely used as model systems to study the glass transition, with much research focused on hard or soft neutral colloids and their mixtures. However, the glass transition of soft-charged spherical colloids and its dynamic effects remain underexplored. This study assesses the glass transition of polymeric multiarm charged soft colloids using shear rheology, coarse-grained molecular dynamics (MD) simulations, and X-ray scattering. Strong particle-particle correlations, driven by electrostatic interarm repulsion, inhibit Newtonian behavior in the dilute regime. The liquid-to-glass transition occurs at just 0.25 wt %, marked by weak caging and minimal interdigitation of arms, as evidenced by particle contact analysis in MD simulations and the strong frequency dependence of the dynamic moduli. Particle shells interdigitate only well within the glassy regime, leading to a nearly frequency-independent rheological response. The weak volume fraction dependence of the yield stress sets these charged systems among the softest colloids reported in the literature.