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Matière Molle
(423) Articles dans des revues
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Polydispersity analysis of Taylor dispersion data: the cumulant method
Auteur(s): Cipelletti L., Biron Jean-Philippe, Martin Fernandez M., Cottet Hervé
(Article) Publié:
Analytical Chemistry, vol. 86 p.6471-6478 (2014)
Texte intégral en Openaccess :
Ref HAL: hal-01058494_v1
Ref Arxiv: 1408.6085
DOI: 10.1021/ac501115y
WoS: 000338488800043
Ref. & Cit.: NASA ADS
Exporter : BibTex | endNote
23 Citations
Résumé: Taylor dispersion analysis is an increasingly popular characterization method that measures the diffusion coefficient, and hence the hydrodynamic radius, of (bio)polymers, nanoparticles or even small molecules. In this work, we describe an extension to current data analysis schemes that allows size polydispersity to be quantified for an arbitrary sample, thereby significantly enhancing the potentiality of Taylor dispersion analysis. The method is based on a cumulant development similar to that used for the analysis of dynamic light scattering data. Specific challenges posed by the cumulant analysis of Taylor dispersion data are discussed, and practical ways to address them are proposed. We successfully test this new method by analyzing both simulated and experimental data for solutions of moderately polydisperse polymers and polymer mixtures.
Commentaires: 41 pages (including Supporting Information), 5 figures (+ 7 figs. in the Supporting Information)
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A microscopic view of the yielding transition in concentrated emulsions
Auteur(s): Knowlton E. D., Pine D. J., Cipelletti L.
(Article) Publié:
Soft Matter, vol. 10 p.6931 (2014)
Texte intégral en Openaccess :
Ref HAL: hal-01058242_v1
PMID 24920407
Ref Arxiv: 1403.4433
DOI: 10.1039/c4sm00531g
WoS: 000341025700007
Ref. & Cit.: NASA ADS
Exporter : BibTex | endNote
91 Citations
Résumé: We use a custom shear cell coupled to an optical microscope to investigate at the particle level the yielding transition in concentrated emulsions subjected to an oscillatory shear deformation. By performing experiments lasting thousands of cycles on samples at several volume fractions and for a variety of applied strain amplitudes, we obtain a comprehensive, microscopic picture of the yielding transition. We find that irreversible particle motion sharply increases beyond a volume-fraction dependent critical strain, which is found to be in close agreement with the strain beyond which the stress-strain relation probed in rheology experiments significantly departs from linearity. The shear-induced dynamics are very heterogenous: quiescent particles coexist with two distinct populations of mobile and 'supermobile' particles. Dynamic activity exhibits spatial and temporal correlations, with rearrangements events organized in bursts of motion affecting localized regions of the sample. Analogies with other sheared soft materials and with recent work on the transition to irreversibility in sheared complex fluids are briefly discussed.
Commentaires: 11 pages, 10 figures. Submitted to Soft Matter
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Tuning Structure and Rheology of Silica-Latex Nanocomposites with the Molecular Weight of Matrix Chains: A Coupled SAXS-TEM-Simulation Approach
Auteur(s): Banc A., Genix A.-C., Chirat M., Dupas C., Caillol Sylvain, Sztucki Michael, Oberdisse J.
(Article) Publié:
Macromolecules, vol. 47 p.3219-3230 (2014)
Texte intégral en Openaccess :
Ref HAL: hal-00993789_v1
Ref Arxiv: 1405.5411
DOI: 10.1021/ma500465n
WoS: 000336020900052
Ref. & Cit.: NASA ADS
Exporter : BibTex | endNote
34 Citations
Résumé: The structure of silica-latex nanocomposites of three matrix chain masses (20, 50, and 160 kg/mol of poly(ethyl methacrylate)) are studied using a SAXS/TEM approach, coupled via Monte Carlo simulations of scattering of fully polydisperse silica nanoparticle aggregates. At low silica concentrations (1 vol. %), the impact of the matrix chain mass on the structure is quantified in terms of the aggregation number distribution function, highest mass leading to individual dispersion, whereas the lower masses favor the formation of small aggregates. Both simulations for SAXS and TEM give compatible aggregate compacities around 10 vol. %, indicating that the construction algorithm for aggregates is realistic. Our results on structure are rationalized in terms of the critical collision time between nanoparticles due to diffusion in viscous matrices. At higher concentrations, aggregates overlap and form a percolated network, with a smaller and lighter mesh in the presence of high mass polymers. The linear rheology is investigated with oscillatory shear experiments. It shows a feature related to the silica structure at low frequencies, the amplitude of which can be described by two power laws separated by the percolation threshold of aggregates.
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Laser Doppler holographic microscopy in transmission: application to fish embryo imaging
Auteur(s): Verrier N., Alexandre D., Gross M.
(Article) Publié:
Optics Express, vol. 22 p.9368 (2014)
Texte intégral en Openaccess :
Ref HAL: hal-00970195_v1
Ref Arxiv: 1404.7781
DOI: 10.1364/OE.22.009368
WoS: 000335902200054
Ref. & Cit.: NASA ADS
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12 Citations
Résumé: We have extended Laser Doppler holographic microscopy to transmission geometry. The technique is validated with living fish embryos imaged by a modified upright bio-microcope. By varying the frequency of the holographic reference beam, and the combination of frames used to calculate the hologram, multimodal imaging has been performed. Doppler images of the blood vessels for different Doppler shifts, images where the flow direction is coded in RGB colors or movies showing blood cells individual motion have been obtained as well. The ability to select the Fourier space zone that is used to calculate the signal, makes the method quantitative.
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Off-Equilibrium Surface Tension in Colloidal Suspensions
Auteur(s): Truzzolillo D., Mora S., Dupas C., Cipelletti L.
(Article) Publié:
Physical Review Letters, vol. 112 p.128303 (2014)
Texte intégral en Openaccess :
Ref HAL: hal-00966355_v1
DOI: 10.1103/PhysRevLett.112.128303
WoS: 000333917400012
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26 Citations
Résumé: We study the fingering instability of the interface between two miscible fluids, a colloidal suspension and its own solvent. The temporal evolution of the interface in a Hele-Shaw cell is found to be governed by the competition between the nonlinear viscosity of the suspension and an off-equilibrium, effective surface tension Γe. By studying suspensions in a wide range of volume fractions, Φ, we show that Γe∼Φ^2, in agreement with Korteweg's theory for miscible fluids. The surface tension exhibits an anomalous increase with particle size, which we account for using entropy arguments.
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Surfactant Behavior of Ionic Liquids Involving a Drug: From Molecular Interactions to Self-Assembly
Auteur(s): Tourne-Peteilh Corine, Coasne Benoit, In M., Brevet David, Devoisselle Jean-Marie, Vioux André, Viau Lydie
(Article) Publié:
Langmuir, vol. 30 p.1229-1238 (2014)
Ref HAL: hal-00948479_v1
DOI: 10.1021/la404166y
WoS: 000331344000006
Exporter : BibTex | endNote
55 Citations
Résumé: Aggregates formed in an aqueous medium by three ionic liquids CnMImIbu made up of 1-alkyl-3-methyl-imidazolium cation (n = 4, 6, 8) and ibuprofenate anion are investigated. Dynamic light scattering (DLS), cryogenic transmission electron microscopy (cryo-TEM), 1H nuclear magnetic resonance measurements, and atom-scale molecular dynamics simulations are used to shed light on the main interactions governing the formation of the aggregates and their composition. At high concentration, mixed micelles are formed with a composition that depends on the imidazolium alkyl chain length. For the shortest alkyl chain, micelles are mainly composed of ibuprofenate anions with some imidazolium cations intercalated between the anions. Upon increasing the alkyl chain length, the composition of the aggregates gets enriched in imidazolium cations and aggregates of stoichiometric composition are obtained. Attractive interactions between these aggregates led to the formation of larger aggregates. As suggested by molecular simulations, these larger aggregates might constitute the early stage of phase separation. Transitions from micelles to vesicles or ribbons are observed due to dilution effects and changes in the chemical composition of the aggregates. We also show that aggregation can be probed using simple microscopic quantities such as radial distribution functions and average solvation numbers.
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