Ref HAL: hal-02462075_v2
DOI: 10.1021/acs.macromol.9b01978
WoS: 000507721500036
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Free solution capillary-electrophoresis (CE) is a powerful separation technique for the characterization of diblock copolymers. In this work, four series of double-hydrophilic anionic and cationic block copolymers, namely, poly(acrylamide)-block-poly(acrylic acid) (PAM-b-PAA), poly(acrylamide)-block-poly((3-acrylamidopropyl)trimethylammonium chloride) (PAM-b-PAPTAC), poly(ethylene oxide)-block-poly(acrylic acid) (PEO-b-PAA) and poly(poly(ethylene glycol) methyl ether acrylate)-block-poly(acrylic acid) (P(PEGA)-b-PAA), were synthesized by reversible additionfragmentation chain transfer (RAFT) polymerization and characterized by CE. The electrophoretic mobility distributions of the copolymers were transformed into distributions of composition ratio by introducing a retardation parameter, Xexp,, that represents the hydrodynamic drag retardation due to the neutral block of the copolymer. A linear correlation between Xexp and the ratio of the degrees of polymerization of each blocks was experimentally established and was consistent with the model of electrophoretic mobility of composite macromolecules with hydrodynamic coupling. Finally, the comparison of the distributions between the different copolymer families was significantly improved by considering the distributions in composition ratio compared to the electrophoretic mobility distributions, since it takes into account the differences in solvation, expansion and drag force according to the chemical nature of the blocks.

Ref HAL: hal-02457032_v1
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Ref HAL: hal-02447824_v1
DOI: 10.1088/1361-648X/ab6741
WoS: 000520157900001
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We address the problem of hybridization between topological surface states and a non-topological flat bulk band. Our model, being a mixture of three-dimensional Bernevig–Hughes–Zhang and two-dimensional pseudospin-1 Hamiltonian, allows explicit treatment of the topological surface state evolution by continuously changing the hybridization between the inverted bands and an additional ‘parasitic’ flat band in the bulk. We show that the hybridization with a flat band lying below the edge of the conduction band converts the initial Dirac-like surface states into a branch below and one above the flat band. Our results univocally demonstrate that the upper branch of the topological surface states is formed by Dyakonov–Khaetskii surface states, known for HgTe since the 1980s. Additionally we explore an evolution of the surface states and the arising of Fermi arcs in Dirac semimetals when the flat band crosses the conduction band.

Ref HAL: hal-02428517_v1
Ref Arxiv: 2001.00912
DOI: 10.1103/PhysRevApplied.13.044079
WoS: 000529842800003
Ref. & Cit.: NASA ADS
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1 Citation
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We demonstrate that magnetic skyrmions with diameters around 60 nm can be stabilized at room temperature and zero external magnetic field in an exchange-biased Pt/Co/NiFe/IrMn multilayer stack. This is achieved through an advanced optimization of the multilayer stack composition in order to balance the different magnetic energies controlling the skyrmion size. Magnetic imaging is performed both with magnetic force microscopy and scanning Nitrogen-Vacancy magnetometry, the latter providing unambiguous measurements at zero external magnetic field. In such samples, we show that exchange bias provides an immunity of the skyrmion spin texture to moderate external magnetic field, in the tens of mT range, which is an important feature for applications as memory devices. These results establish exchange-biased multilayer stacks as a promising platform towards the effective realization of memory and logic devices based on magnetic skyrmions.

Commentaires: 5 pages, 3 figures

Ref HAL: hal-02431447_v1
DOI: 10.1103/PhysRevLett.124.013903
WoS: 000505997600005
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2 Citations
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We study the Casimir torque between two metallic one-dimensional gratings rotated by an angle θ with respect to each other. We find that, for infinitely extended gratings, the Casimir energy is anomalously discontinuous at θ 1⁄4 0, due to a critical zero-order geometric transition between a 2D- and a 1D-periodic system. This transition is a peculiarity of the grating geometry and does not exist for intrinsically anisotropic materials. As a remarkable practical consequence, for finite-size gratings, the torque per area can reach extremely large values, increasing without bounds with the size of the system. We show that for finite gratings with only ten period repetitions, the maximum torque is already 60 times larger than the one predicted in the case of infinite gratings. These findings pave the way to the design of a contactless quantum vacuum torsional spring, with possible relevance to micro- and nanomechanical devices.

Ref HAL: hal-02431405_v1
DOI: 10.1016/j.ijheatmasstransfer.2020.119305
WoS: WOS:000518492200034
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7 Citations
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In this paper, magnetoplasmonic manipulation of near-field radiative heat transfer (NFRHT) is realized using two twisted graphene gratings. As a result of the quantum Hall regime of magneto-optical graphene and the grating effect, three types of graphene surface plasmon polaritons (SPPs) modes are observed in the system: near-zero modes, high-frequency hyperbolic modes, and elliptic modes. The elliptic SPPs modes, which are caused by the combined effect of magnetic field and grating, are observed in the graphene grating system for the first time. In addition, the near-zero modes can be greatly enhanced by the combined effect grating and magnetic field, rendering graphene devices promising for thermal communication at ultra-low frequency. In particular, the near-zero modes result in a unique enhancement region of heat transfer, no matter for any twisted angle between gratings. The combined effect of grating and magnetic field is investigated simultaneously. By changing the strength of magnetic field, the positions and intensities of the modes can be modulated, and hence the NFRHT can be tuned accordingly, no matter for parallel or twisted graphene gratings. The magnetic field endows the grating action (graphene filling factors and twisted angles) with a higher modulation ability to modulate the NFRHT compared with zero-field. Moreover, the modulation ability of twist can be tuned by the magnetic field at different twisted angles. In sum, the combined effect of magnetic field and grating provides a tunable way to realize the energy modulation or multi-frequency thermal communications related to graphene devices.

Ref HAL: hal-02526695_v1
DOI: 10.1016/j.rehab.2019.10.009
WoS: 000549977400001
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Few rehabilitation methods have proven their efficacy in increasing sensori-motor recovery and/or function of the upper limb (UL) after stroke. Video games (VGs) are promising tools in this indication.OBJECTIVE: To compare UL rehabilitation by using VGs and conventional rehabilitation (CR) in patients with sub-acute stroke.DESIGN: Single-blind, multicentric trial, with central randomization and stratification by center.SETTING: Physical and rehabilitation medicine departments of 2 university hospitals.PARTICIPANTS: Adults within 3 months after a first vascular cerebral accident, with UL Fugl Meyer Score (UL-FMS)<30/66 and without major cognitive impairment.INTERVENTION: A 45-min additional session of conventional occupational therapy (OT) or a VG-based OT session as add-on therapy to usual rehabilitation programs, 5 days/week for 6 weeks.MAIN OUTCOME MEASURES: Primary outcome: UL-FMS. Secondary outcome: Box and Block Test (BBT), Wolf Motor Function test (WMFT), Motor Activity Log (MAL), Barthel Index and quality of life (SF-36).RESULTS: We included 51 patients (20 women) at a mean (SD) of 27.2 (19.4) days post-stroke (mean age 58 years [range 24-83]), 26 in the CR group and 25 in the VG group (23 in each group at 6-month follow-up). The mean duration of the additional rehabilitation session was similar in both groups: 29.3 (4.3) vs 28.0 (4.4) min in CR and VG groups. Shoulder pain occurred in 4 patients in the VG group versus 7 in the CR group. At day 45, gain in UL-FMS did not significantly differ between the groups (CR mean 17.8 [14.6] vs VG 24.1 [14.8]; P=0.10), whereas gain in BBT was doubled in the VG group (CR 7.4 [12.2] vs VG 15.7 [16.3]; P=0.02). At 6-month follow-up, the study was inconclusive about between-group differences in UL-FMS, BBT and other criteria. Post-hoc analysis showed that gains in UL-FMS or BBT were significantly higher in the VG than CR group for patients included within 30 days post-stroke.CONCLUSION: In general, we cannot conclude that video gaming and conventional OT led to different long-term sensorimotor recovery of the UL after sub-acute stroke. However, when applied within the first month after stroke, video gaming was more efficient than conventional rehabilitation on both sensorimotor recovery and gross grasping function.