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Confinement dans les nanotubes
(10) Production(s) de l'année 2021
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Nonlinear field dependent conductivity dielectrics made of graphite nanoplatelets filled composites 
Auteur(s): Metz R. , Blanc C., Dominguez S., Tahir S., Le Parc R., Hassanzadeh M.
(Article) Publié:
Materials Letters, vol. 292 p.129611 (2021)
Texte intégral en Openaccess : 
Ref HAL: hal-03245508_v1
DOI: 10.1016/j.matlet.2021.129611
WoS: WOS:000639094100055
Exporter : BibTex | endNote
Résumé: Downsizing electronic and electric equipment requires the optimization of electric field distributions in order to avoid localized dielectric breakdown (also called partial discharges). This paper presents a novel dielectric composite material aimed at grading electrical local surface stress. This functional material has a conductivity which increases by several orders with the applied electric field giving the ability to distribute the field by itself. It is prepared for the first time by dispersing graphite nanoplatelets in a polymer and may be used as a resistive or capacitive field grading material in electronic and electrical applications. Mechanisms at the origin of the nonlinear behavior are discussed.
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Comment on the paper “Improving Poor Man’s Kramers-Kronig analysis and Kramers-Kronig constrained variational analysis”
Auteur(s): Rousseau E., Izard N., Bantignies J.-L., Felbacq D.
(Article) Publié:
-Spectrochimica Acta Part A Molecular And Biomolecular Spectroscopy [1994-...], vol. 259 p.119849 (2021)
Texte intégral en Openaccess : 
Ref HAL: hal-03228703_v1
DOI: 10.1016/j.saa.2021.119849
Exporter : BibTex | endNote
Résumé: We clarify some analytical expressions existing in the literature, • Within the correct formulae we conclude that there is no need for an ad hoc improvement on the opposite to the title paper, • We highlight the symmetry properties of the function to be integrated in order to agree with the usual assumptions made to derive the Kramers-Kronig relations, • The analytical formula we provide may be used to increase the accuracy of the "Poor Man's Kramers-Kronig analysis" method and the "Kramers-Kronig constrained variational analysis" method.
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Raman resonance tuning of quaterthiophene in filled carbon nanotubes at high pressures
Auteur(s): Alencar R. S., Aguiar A. L., Ferreira R. S., Chambard R., Jousselme B., Bantignies J.-L., Weigel C., Clement S., Aznar R., Machon D., Souza Filho A. G., San-Miguel A., Alvarez L.
(Article) Publié:
Carbon, vol. 173 p.163-173 (2021)
Texte intégral en Openaccess :
Ref HAL: hal-03163018_v1
DOI: 10.1016/j.carbon.2020.10.083
WoS: WOS:000613132200003
Exporter : BibTex | endNote
Résumé: Filling carbon nanotubes with molecules is a route for the development of electronically modified one-dimensional hybrid structures for which the interplay between the electronic structure of molecules and nanotubes is a key factor. Tuning these energy levels with external parameters is an interesting strategy for the engineering of new devices and materials. Here we show that the hybrid system composed by quaterthiophene (4T) molecules confined in single-walled carbon nanotubes, presents a piezo-Raman-resonance of the molecule vibrational pattern. This behavior manifests as a rapid pressure induced enhancement of the 4T Raman mode intensities compared to the tubes G-band Raman modes. Density functional theory calculations allow to explain the spectral behaviour through the pressure-enhanced quaterthiophene resonance evolution. By increasing pressure, the tube cross-section deformation leads to a reduction of the intermolecular distance, to the splitting of the molecular levels and then to an increase of resonance channels. Calculations and experiments converge to the 4T piezo-resonance scenario associated with the pressure-induced nanotube radial collapse observed at about 0.8 GPa. Our findings offer possibilities for the development of pressure transducers based on molecule-filled carbon nanotubes.
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