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Matière Molle & Verres
(26) Production(s) de l'année 2023
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Dynamics of prolate spheroids in the vicinity of an air–water interface
Auteur(s): Villa S., Larobina Domenico, Stocco A., Blanc C., Villone Massimiliano, d'Avino Gaetano, Nobili M.
(Article) Publié:
Soft Matter, vol. 19 p.2646-2653 (2023)
Texte intégral en Openaccess :
Ref HAL: hal-04072095_v1
PMID 36967649
DOI: 10.1039/D2SM01665F
Exporter : BibTex | endNote
Résumé: In this article, we present the mobilities of prolate ellipsoidal micrometric particles close to an air–water interface measured by dual wave reflection interference microscopy. Particle's position and orientation with respect to the interface are simultaneously measured as a function of time. From the measured mean square displacement, five particle mobilities (3 translational and 2 rotational) and two translational–rotational cross-correlations are extracted. The fluid dynamics governing equations are solved by the finite element method to numerically evaluate the same mobilities, imposing either slip and no-slip boundary conditions to the flow at the air–water interface. The comparison between experiments and simulations reveals an agreement with no-slip boundary conditions prediction for the translation normal to the interface and the out-of-plane rotation, and with slip ones for parallel translations and in-plane rotation. We rationalize these evidences in the framework of surface incompressibility at the interface.
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Discussion about suitable applications for biodegradable plastics regarding their sources, uses and end of life
Auteur(s): Paul-Pont Ika, Ghiglione Jean-François, Gastaldi Emmanuelle, ter Halle Alexandra, Huvet Arnaud, Bruzaud Stéphane, Lagarde Fabienne, Galgani François, Duflos Guillaume, George M., Fabre P.
(Article) Publié:
Waste Management, vol. 157 p.242-248 (2023)
Ref HAL: hal-04186887_v1
PMID 36577275
DOI: 10.1016/j.wasman.2022.12.022
WoS: 000972939800001
Exporter : BibTex | endNote
Résumé: This opinion paper offers a scientific view on the current debate of the place of biodegradable plastics as part of the solution to deal with the growing plastic pollution in the world's soil, aquatic, and marine compartments. Based on the current scientific literature, we focus on the current limits to prove plastic biodegradability and to assess the toxicity of commercially used biobased and biodegradable plastics in natural environments. We also discuss the relevance of biodegradable plastics for selected applications with respect to their use and end of life. In particular, we underlined that there is no universal biodegradability of plastics in any ecosystem, that considering the environment as a waste treatment system is not acceptable, and that the use of compostable plastics requires adaptation of existing organic waste collection and treatment channels.
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Gelation and Re-entrance in Mixtures of Soft Colloids and Linear Polymers of Equal Size
Auteur(s): Parisi Daniele, Truzzolillo D., Slim Ali, Dieudonne-George P., Narayanan Suresh, Conrad Jacinta, Deepak Vishnu, Gauthier Mario, Vlassopoulos Dimitris
(Article) Publié:
Macromolecules, vol. 56 p.1818-1827 (2023)
Texte intégral en Openaccess :
Ref HAL: hal-04035012_v1
Ref Arxiv: 2212.05992
DOI: 10.1021/acs.macromol.2c02491
Ref. & Cit.: NASA ADS
Exporter : BibTex | endNote
Résumé: Liquid mixtures composed of colloidal particles and much smaller non-adsorbing linear homopolymers can undergo a gelation transition due to polymer-mediated depletion forces. We now show that the addition of linear polymers to suspensions of soft colloids having the same hydrodynamic size yields a liquid-to-gel-to-re-entrant liquid transition. In particular, the dynamic state diagram of 1,4-polybutadiene star–linear polymer mixtures was determined with the help of linear viscoelastic and small-angle X-ray scattering experiments. While keeping the star polymers below their nominal overlap concentration, a gel was formed upon increasing the linear polymer content. Further addition of linear chains yielded a re-entrant liquid. This unexpected behavior was rationalized by the interplay of three possible phenomena: (i) depletion interactions, driven by the size disparity between the stars and the polymer length scale which is the mesh size of its entanglement network; (ii) colloidal deswelling due to the increased osmotic pressure exerted onto the stars; and (iii) a concomitant progressive suppression of the depletion efficiency on increasing the polymer concentration due to reduced mesh size, hence a smaller range of attraction. Our results unveil an exciting new way to tailor the flow of soft colloids and highlight a largely unexplored path to engineer soft colloidal mixtures.
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Hidden traces of chirality in the fluctuations of a fully unwound cholesteric
Auteur(s): Poy G.
(Article) Publié:
Soft Matter, vol. 19 p.1115-1130 (2023)
Texte intégral en Openaccess :
Ref HAL: hal-03953472_v1
DOI: 10.1039/D2SM01646J
Exporter : BibTex | endNote
Résumé: Confinement and hydrodynamic interactions often play an important role in the fluctuation dynamics of soft matter systems, which can typically be studied using light scattering techniques. With experimental and theoretical methodologies, I demonstrate here that chirality is an additional critical parameter that leads to diverging decay times and correlation lengths in chiral liquid crystal cells with a fully unwound cholesteric helix. This study combines light scattering measurements made in a tailored microscope geometry and theoretical calculations of the decay dynamics of chiral orientational fluctuations---including hydrodynamics---to establish the existence of two soft chiral modes of fluctuations driving the destabilization of the unwound cholesteric. Despite the achirality of the equilibrium state of unwound cholesterics, this study indicates that chirality hides itself in the orientational fluctuation modes and plays a major role in their dynamics, which can be exploited to locally measure the strength of chirality in frustrated chiral liquid crystal cells.
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Transfer of multi-DNA patches by colloidal stamping
Auteur(s): Khalaf Rawan, Viamonte Andrea, Ducrot Etienne, Merindol R., Ravaine Serge
(Article) Publié:
Nanoscale, vol. 15 p.573-577 (2023)
Texte intégral en Openaccess :
Ref HAL: hal-03932109_v1
Ref Arxiv: 2301.05515
DOI: 10.1039/d2nr05016a
Ref. & Cit.: NASA ADS
Exporter : BibTex | endNote
Résumé: Patchy particles have received great attention due to their ability to develop directional and selective interactions and serve as building units for the self-assembly of innovative colloidal molecules and crystalline structures. Although synthesizing particles with multiple dissimilar patches is still highly challenging and lacks efficient methods, these building blocks would open paths towards a broader range of ordered materials with inherent properties. Herein, we describe a new approach to pattern functional DNA patches at the surface of particles, by the use of colloidal stamps. DNA inks are transferred only at the contact zones between the target particles and the stamps thanks to selective strand-displacement reactions. The produced DNA-patchy particles are ideal candidates to act as advanced precision/designer building blocks to self-assemble the next generation of colloidal materials.
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